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phosphorous acid : ウィキペディア英語版
phosphorous acid

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Phosphorous acid is the compound described by the formula H3PO3. This acid is diprotic (readily ionizes two protons), not triprotic as might be suggested by this formula. Phosphorous acid is an intermediate in the preparation of other phosphorus compounds.
==Nomenclature and tautomerism==

H3PO3 is more clearly described with the structural formula HPO(OH)2. This species exists in equilibrium with a minor tautomer P(OH)3. IUPAC recommendations, 2005, are that the latter be called phosphorous acid, whereas the dihydroxy form is called phosphonic acid.〔.〕 Only the reduced phosphorus compounds are spelled with an "ous" ending.
The P(OH)3 tautomer has been observed as a ligand bonded to molybdenum.
Other important oxyacids of phosphorus are phosphoric acid (H3PO4) and hypophosphorous acid (H3PO2). The reduced phosphorus acids are subject to similar tautomerism involving shifts of H between O and P.

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